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(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%, also known as (S)-3,5-t-Bu-MeOBIPHEP, is a white powder chemical compound. It is a type of ligand that is sold in collaboration with Solvias AG. (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% is characterized by its unique chemical structure, which includes di-t-butylphenyl groups and a biphenyl core with phosphino and methoxy substituents. Its high purity (minimum 97%) ensures its effectiveness in various applications.

167709-31-1

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167709-31-1 Usage

Uses

Used in Chemical Synthesis:
(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% is used as a ligand in the stereoselective preparation of allenoates. This application takes advantage of its ability to facilitate palladium-catalyzed asymmetric carbonylation of propargylic carbonates, leading to the formation of chiral allenoates with high selectivity.
Used in C-C Coupling Reactions:
In the field of organic chemistry, (S)-3,5-t-Bu-MeOBIPHEP is utilized as a ligand for C-C coupling reactions. Its unique structure allows it to effectively promote the formation of carbon-carbon bonds, which are crucial in the synthesis of various complex organic molecules and pharmaceutical compounds.
Used in Pharmaceutical Industry:
(S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% is used as a ligand for the development of novel drug candidates in the pharmaceutical industry. Its ability to participate in stereoselective reactions and C-C coupling reactions makes it a valuable tool for the synthesis of complex molecules with potential therapeutic applications.
Used in Catalyst Development:
In the field of catalysis, (S)-3,5-t-Bu-MeOBIPHEP is used as a ligand for the development of new catalysts. These catalysts can be employed in various chemical reactions, including those involving asymmetric synthesis and C-C coupling, to improve reaction efficiency and selectivity.

Reactions

Pd-catalyzed enantioselective Heck reaction. Used in enantioselective lactam synthesis via Pd-catalyzed intramolecular allylic alkylation. Used in enantioselective Au-catalyzed polycyclization reactions.

Check Digit Verification of cas no

The CAS Registry Mumber 167709-31-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,6,7,7,0 and 9 respectively; the second part has 2 digits, 3 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 167709-31:
(8*1)+(7*6)+(6*7)+(5*7)+(4*0)+(3*9)+(2*3)+(1*1)=161
161 % 10 = 1
So 167709-31-1 is a valid CAS Registry Number.

167709-31-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:167709-31-1 SDS

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