1679-14-7Relevant academic research and scientific papers
Preparation and Some Properties of 7,7-Dilithionorbornane
Vlaar, Cornelis P.,Klumpp, Gerhard W.
, p. 2951 - 2952 (1991)
7,7-Dilithionorbornane 4a is formed from 7,7-dibromonorbornane 4b by reduction with 4.5 equiv of lithium p,p'-di-tert-butylbiphenyl at -100 deg C, at which temperature it adds to ethylene.On warming it rearranges to 1-lithio-5-(2-lithioethyl)cyclopentene 5.
Oxidative coupling of 7,7-dilithionorbornane; 7,7′-dilithio-7,7′-dinorbornyl, a new vic-dilithioalkane prone to a new mode of decomposition
Vlaar, Cornelis P.,Klumpp, Gerhard W.
, p. 4651 - 4654 (1993)
7,7-Dilithionorbornane reacts with butyl halides at -100°C to give 7,7′-dilithio-7,7′-dinorbornyl (30%), which is easily oxidized to 7,7′-dinorbornylidene.
Reactions over Supported Metal Catalysts. VI.The Effect of Halogen Compounds on Transition Metal Catalysts Supported on Silica or Pumice. Reactions of 3-Methylnortricyclene
Jackson, W. Roy,Nicolson, David M.
, p. 2261 - 2269 (2007/10/02)
The product
