167907-23-5Relevant academic research and scientific papers
Trifluoromethanesulfinamide from ephedrine: A more efficient trifluoromethylating reagent
Roussel, Solveig,Billard, Thierry,Langlois, Bernard R.,Saint-Jalmes, Laurent
, p. 2119 - 2122 (2004)
Nucleophilic trifluoromethylation of non-enolizable and enolizable carbonyl compounds was achieved with the trifluoromethanesulfinamide derived from O-silylated ephedrine. In contrast to the trifluoroacetamide analog, previously described, this reagent is able to trifluoromethylate more acidic enolizable compounds.
1,1,1-trifluoro-3-phenyl-2-butyl p-nitrobenzoate
Faure, Rene,Felix, Caroline,Laurent, Andre,Mison, Pierre
, p. 1935 - 1937 (1997)
The reduction of the trifluoromethylated ketone, 1,1,1-trifluoro-3-phenyl-2-butanone, (1), or its hydrogenated homologue, 3-phenyl-2-butanone, (2), with lithium aluminium hydride (LAH) gave 1,1,1-trifluoro-3-phenyl-2-butanol, (4), or 3-phenyl-2-butanol, (
