167960-76-1Relevant academic research and scientific papers
Reaction of ruthenium phenyl acetylide with iron-chalcogen clusters and iron pentacarbonyl
Mathur, Pradeep,Raghuvanshi, Abhinav,Ji, Radhe Shyam,Mobin, Shaikh M.
, p. 55 - 60 (2013/05/21)
Photolysis of a THF solution containing ruthenium acetylide [(η5-C5H5)Ru(PPh3) 2(η1-CCPh)] with [Fe3(CO) 9(μ3-Se)2] cluster affords an adduct [{μ-SeC(CpRu(PPh3)(CO))C(Ph)Se}(CO)6Fe2] (1), while under similar reaction condition with [Fe3(CO) 9(μ3-Te)2] cluster a Ru-inserted product [(η5-C5H5)(PPh3) (η1-CCPh)RuFe2(μ3-Te) 2(CO)6] (2) was obtained. Under thermal condition [(η5-C5H5)Ru(PPh3) 2(η1-CCPh)] react with Fe(CO)5 to give an acetylide stabilised Fe2Ru mixed metal cluster [(η5- C5H5)RuFe2(CO)7(η2: η2:η1-CCPh)], (3).
One-step syntheses of Ph3P-substituted selenido carbonyl iron and ruthenium clusters Part 2. Crystal structures of Fe2(μ2-Se2)(CO)6-n(PPh 3)n(n = 1 or 2), Fe3(μ3<
Baistrocchi, Paolo,Careri, Maria,Cauzzi, Daniele,Graiff, Claudia,Lanfranchi, Maurizio,Manini, Paola,Predieri, Giovanni,Tiripicchio, Antonio
, p. 367 - 374 (2008/10/08)
Ph3PSe reacts with Fe3(CO)12 giving six products (1-6) belonging to three different families of clusters: Fe2(μ-Se2)(CO)6-nLn (two products, 3, 5, n = 1, 2), Fe3(μsub
