167967-07-9

Basic information

• Product Name: 1-cyclohexene-1-carboxylic acid benzyl ester
• Synonyms: 1-cyclohexene-1-carboxylic acid benzyl ester
• CAS NO: 167967-07-9
• Molecular Weight: 216.28
• Mol File: 167967-07-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-cyclohexene-1-carboxylic acid benzyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1-cyclohexene-1-carboxylic acid benzyl ester(167967-07-9)
• EPA Substance Registry System: 1-cyclohexene-1-carboxylic acid benzyl ester(167967-07-9)

Safety Data

• Hazardous Substances Data: 167967-07-9(Hazardous Substances Data)

Upstream product

• 636-82-8 cyclohexene-1-carboxylic acid 
• 100-51-6 benzyl alcohol 
• 201230-82-2 carbon monoxide 
• 28075-50-5 cyclohex-1-en-1-yl trifluoromethane sulfonate 
• 108-94-1 cyclohexanone 

Downstream Products

• 1052689-97-0 C₁₃H₂₀O 

Relevant articles and documents

Pd-Catalyzed Carbonylation of Vinyl Triflates to Afford α,β-Unsaturated Aldehydes, Esters, and Amides under Mild Conditions

An efficient and general protocol for the synthesis of α,β-unsaturated aldehydes, esters, and amides via carbonylation of vinyl triflates including derivatives of camphor, ketoisophorone, verbenone, and pulegone was developed. Crucial for these transformations is the use of a specific palladium catalyst containing a pyridyl-substituted dtbpx-type ligand. This procedure also allows for an easy access of dicarbonylated products from the corresponding ketones.

Oxazoline N-oxide-mediated [2+3] cycloadditions: New access to quaternary asymmetric centres

Cycloadditions between camphor-derived oxazoline N-oxide 1 and dipolarophiles 5 or 8 afforded adducts 6 and 9, respectively, with almost complete regio- and stereoselectivity depending on the substitution patterns of the dipolarophiles. Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.