16797-75-4

Upstream product

• 2944-05-0 carbon monosulfide 
• 54396-68-8 3-diazo-2,2,4,4-tetramethylpentane 
• 603-35-0 triphenylphosphine 
• 756860-79-4 3,3-di-tert-butylthiirane-2-thione 
• 120033-92-3 ((CH₃)3C)2C(CSGe)(C₆H₂(CH₃)3)2 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 

Downstream Products

• 33512-45-7 3,6-di-tert-butyl-2,2,7,7,-tetramethyl-3,4,5-octatriene 
• 16797-76-5 3,3-di-tert-butylthioketene S-oxide 
• 56956-25-3 2,2,4,4-tetramethylpentane-3-thione S-oxide 
• 79265-24-0 methyl 1-tert-butyl-3,3-dimethyl-2-oxobutanesulfinate 
• 108-80-5 cyanuric acid 
• 77298-03-4 3,3-Di-tert-butyl-4-thioxo-2-azetidinon 
• 127597-25-5 C₁₇H₂₅NS 
• 112222-07-8 2-tert-Butyl-3,3-dimethylthiobuttersaeure-O-phenylester 
• 112222-06-7 3,3-Di-tert-butyl-1-(phenoxysulfonyl)-4-thioxo-2-azetidinon 
• 39195-77-2 1-methoxy-3,3-dimethylbutan-2-one 
• 29679-00-3 3,6-di-tert-butyl-2,2,7,7-tetramethyl-octane-4,5-dione 
• 88181-01-5 2,2-di-tert-butylthioacetophenone 
• 98687-83-3 1,2-Bis-(2,2,6,6-tetramethyl-cyclohexyl)-ethane-1,2-dione 
• 10507-31-0 (E)-2,2,7,7-Tetramethyl-oct-4-ene-3,6-dione 

Relevant academic research and scientific papers

Synthesis and reaction of α-dithiolactone

Treatment of di-tert-butylthioketene S-oxide (5a) with Lawesson reagent at room temperature resulted in the formation of 3,3-di-fert-butylthiirane-2-thione (4a) in high yield. The oxidation of 4 a with mCPBA (mCPBA = m-chloroperbenzioc acid) gave 3,3-di-ferf-butylthiirane-2-thione S-oxide (6) almost quantitatively. The reactions of 4 a with dimethyl acetyle nedicarboxylate (DMAD) and benzyne afforded dimethyl 2-(2,2,4,4-tetramethylpentan-3-ylidene)-1, 3-dithiole-4,5-dicarboxylate (13) and 2-(2,2,4,4-tetramethylpentan-3-ylidene) benzo[d] [1,3]-dithiole (15), respectively, in high yields, suggesting that 4 a is an excellent 1,3-dipole. The reaction of 4 a with ethylenebis(triphenylphosphine)platinum (16) gave dithiolato-platinum complex (22) in high yield. The structure of 22 was determined by X-ray crystallographic analysis.

3-Alkylidenethiagermiranes

Dimethyl- and diphenylgermylenes react with di-tert-butylthioketene to give 4-alkylidene-1,2,3-thiadigermetanes 2 and 4, the products of the insertion of germylenes into 3-alkylidenethiagermiranes. Dimesitylgermylene generated by the thermolysis of hexamesitylcyclotrigermane (12) at 80°C reacts with di-tert-butylthioketene to produce a stable 3-alkylidenethiagermirane, 13. Photolysis of 13 produces dimesitylgermylene and di-tert-butylthioketene via germathiocarbonyl ylide 17, which is intensely blue in color with a maximum band at 580 nm. 13 reacts with dimethylgermylene to yield the corresponding 4-alkylidene-1,2,3-thiadigermetane 22. Oxidation of 13 by m-chloroperbenzoic acid gives 3-alkylidene-1,2,4-oxathiagermetane S-oxide 23.