168086-20-2

Usage

Molecular structure

1,3-bis(2-bicyclo[4.2.0]octa-1,3,5-trien-3-yl-ethenyl)-1,1,3,3-tetramethyldisiloxane has a complex molecular structure with two molecules of the bicyclo[4.2.0]octa-1,3,5-trien-3-yl-ethenyl group and a tetramethyldisiloxane group.

Symmetry

The molecule is symmetrical due to the presence of two identical bicyclo[4.2.0]octa-1,3,5-trien-3-yl-ethenyl groups.

Tetramethyldisiloxane group

The molecule contains a tetramethyldisiloxane group, which consists of two silicon atoms connected by oxygen atoms.

Siloxane compound

It is a derivative of the class of siloxane compounds, which are known for their wide range of industrial applications.

Industrial applications

Siloxane compounds, including 1,3-bis(2-bicyclo[4.2.0]octa-1,3,5-trien-3-yl-ethenyl)-1,1,3,3-tetramethyldisiloxane, are used as lubricants, hydraulic fluids, and in the production of silicone polymers.

Chemical behavior and reactivity

The specific properties and potential uses of 1,3-bis(2-bicyclo[4.2.0]octa-1,3,5-trien-3-yl-ethenyl)-1,1,3,3-tetramethyldisiloxane would depend on its exact chemical behavior and reactivity, which would require further investigation and study.

Further research

To fully understand the properties and potential applications of 1,3-bis(2-bicyclo[4.2.0]octa-1,3,5-trien-3-yl-ethenyl)-1,1,3,3-tetramethyldisiloxane, additional research and study are necessary.

Upstream product

• 3277-26-7 1,1,3,3-Tetramethyldisiloxane 
• 144597-22-8 C₁₀H₈ 

Relevant academic research and scientific papers

A Ligand-Free Pt3Cluster Catalyzes the Markovnikov Hydrosilylation of Alkynes with up to 106Turnover Frequencies

The Pt-catalyzed hydrosilylation of alkynes is the procedure of choice to obtain vinylsilanes, and is claimed to be the most relevant application of Pt in organic synthesis. More than half a century after its discovery, only β-vinylsilanes (anti-Markovnikov addition) are obtained with simple Pt catalysts, whereas α-vinylsilanes (Markovnikov addition) remain elusive compounds. Here the catalysis of the Markovnikov hydrosilylation of terminal alkynes by Pt3clusters, in parts-per-million amounts, to give a wide variety of α-vinylsilanes in reasonable isolated yields and with turnover frequencies that can reach up to one million per hour is reported. Moreover, these α-vinylsilanes are reactive in well-stablished C?C bond-forming cascade reactions, in which the corresponding β-isomers are unreactive. Besides its efficiency and synthetic usefulness, this catalytic system is an excellent example of how the atom-by-atom aggregation of a catalytic metal leads to a different selectivity for a given reaction.

Preparation of vinyl silyl ethers and disiloxanes via the silyl-heck reaction of silyl ditriflates

Vinyl silyl ethers and disiloxanes can now be prepared from aryl-substituted alkenes and related substrates using a silyl-Heck reaction. The reaction employs a commercially available catalyst system and mild conditions. This work represents a highly practical means of accessing diverse classes of vinyl silyl ether substrates in an efficient and direct manner with complete regiomeric and geometric selectivity.