168211-64-1

Basic information

• Product Name: 2-[2-(2-{2-[5-(2-{2-[2-(2-hydroxy-ethoxy)-ethoxy]-ethoxy}-ethoxy)-naphthalen-1-yloxy]-ethoxy}-ethoxy)-ethoxy]-ethanol
• Synonyms: 2-[2-(2-{2-[5-(2-{2-[2-(2-hydroxy-ethoxy)-ethoxy]-ethoxy}-ethoxy)-naphthalen-1-yloxy]-ethoxy}-ethoxy)-ethoxy]-ethanol
• CAS NO: 168211-64-1
• Molecular Weight: 512.598
• Mol File: 168211-64-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-[2-(2-{2-[5-(2-{2-[2-(2-hydroxy-ethoxy)-ethoxy]-ethoxy}-ethoxy)-naphthalen-1-yloxy]-ethoxy}-ethoxy)-ethoxy]-ethanol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[2-(2-{2-[5-(2-{2-[2-(2-hydroxy-ethoxy)-ethoxy]-ethoxy}-ethoxy)-naphthalen-1-yloxy]-ethoxy}-ethoxy)-ethoxy]-ethanol(168211-64-1)
• EPA Substance Registry System: 2-[2-(2-{2-[5-(2-{2-[2-(2-hydroxy-ethoxy)-ethoxy]-ethoxy}-ethoxy)-naphthalen-1-yloxy]-ethoxy}-ethoxy)-ethoxy]-ethanol(168211-64-1)

Safety Data

• Hazardous Substances Data: 168211-64-1(Hazardous Substances Data)

Downstream Products

• 1280220-36-1 C₅₆H₇₈N₆O₁₀ 
• 945529-16-8 BHEEEEN monotosylate 
• 158394-33-3 1,5-bis[2-[2-[2-(2-hydroxyethoxy)ethoxy]ethoxy]ethoxy]naphthalene bis(4-methylbenzenesulfonate) 
• 668493-31-0 1,5-bis[2-[2-[2-[2-(triisopropylsilyloxy)ethoxy]ethoxy]ethoxy]ethoxy]naphthalene 
• 1295300-33-2 C₆₂H₈₀O₁₀ 
• 1269780-58-6 C₆₅H₈₄O₁₂ 

Relevant articles and documents

Catalysis in the Self-Assembly of [2]Rotaxanes and [2]Pseudorotaxanes. Effect of the Length of Polyethereal Side Arms and Terminal Stoppers

The template effects exerted by compounds 3, 5, 6, and 8 in the ring closure reaction of the trication 13+ to yield the [2] pseudorotaxanes 154+ and 174+ and the [2]rotaxanes 18 4+ and 204+ have been quantitatively evaluated in acetonitrile at 62 °C by UV/vis spectrophotometry. The rate of ring closure of the trication 13+ largely increases in the presence of the templates up to a maximum of ca. 200 times in the case of 5 at a concentration of ca. 0.08 M. The results indicate that, in the self-assembly of a rotaxane, the template effect of the guest is lowered by the presence of two large stoppers (triisopropylsilyl) at the end of the linear chains; this effect is more important the shorter the chain and can be mainly ascribed to steric effects. Previously hypothesized entropic effects appear to be of lesser importance.