168331-80-4Relevant academic research and scientific papers
Study of the reaction of 3,6-di-tert-butyl-o-benzoquinone with organozinc and organocadmium compounds
Kurskii, Yu. A.,Druzhkov,Egorochkin,Abakumov
, p. 37 - 42 (2016/03/12)
The effect of substituents in the reactions of 3,6-di-tert-butyl-o-benzoquinone with organozinc and organocadmium compounds, leading to three types of products: 3-alkyl-6-tert-butyl-o-benzoquinones, 4-alkyl-3,6-di-tert-butyl-o-benzoquinones, and 2-alkoxy-(or 2-phenoxy)-3,6-di-tert-butylphenols. Correlation analysis gave evidence to show that the first- and second-type products are formed by nucleophilic 1,2- and 1,4-addition, while substituted phenols result from single-electron transfer.
Reaction on the addition of some organometallic compounds to 3,6-di-tert-butyl-o-benzoquinone: new o-quinones
Abakumov, G. A.,Cherkasov, V. K.,Abakumova, L. G.,Nevodchikov, V. I.,Druzhkov, N. O.,et al.
, p. 127 - 134 (2007/10/02)
3,6-Di-tert-butyl-o-benzosemiquinone is very convenient for the investigation of the interaction between organometallic R2M and carbonyl compounds.The reaction of organometallic compounds R2M with o-quinone, where R = Ph, Me, Et, Pr, iPr or su
