168415-01-8Relevant articles and documents
CO-transfer carbonylation reactions. A catalytic pauson-khand-type reaction of enynes with aldehydes as a source of carbon monoxide
Morimoto, Tsumoru,Fuji, Koji,Tsutsumi, Ken,Kakiuchi, Kiyomi
, p. 3806 - 3807 (2007/10/03)
The reaction of enynes with aldehydes in the presence of a catalytic amount of [RhCl(cod)]2/dppp results in the Pauson-Khand-type reaction without the use of gaseous carbon monoxide to give bicyclic cyclopentenones in high yields (14 examples).