16848-25-2

Upstream product

• 2946-01-2 (3aR,5R,6S,6aR)-5-((R)-1,2-dihydroxyethyl)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-6-yl 4-methylbenzenesulfonate 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 78785-31-6 1-O-Acetyl-4-desoxy-3-O-formyl-4-C-methyl-2-O-(4-methylphenylsulfonyl)-β-D-arabinopyranose 
• 78785-30-5 1-O-Acetyl-4-desoxy-3-O-formyl-4-C-methyl-2-O-(4-methylphenylsulfonyl)-α-D-arabinopyranose 
• 78785-05-4 5-Desoxy-1,2-O-isopropyliden-5-C-methyl-3-O-(4-methylphenylsulfonyl)-β-L-idofuranose 
• 78785-05-4 (3aR,5R,6S,6aR)-5-((R)-1-hydroxypropan-2-yl)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-6-yl4-methyl benzenesulfonate 
• 78785-03-2 (3aR,5S,6R,6aR)-5-acetyl-2,2-dimethyltetrahydrofuro[2,3-d]-[1,3]dioxol-6-yl 4-methylbenzenesulfonate 
• 78785-07-6 6-O-Benzyl-5-desoxy-1,2-O-isopropyliden-5-C-methyl-3-O-(4-methylphenylsulfonyl)-β-L-idofuranose 
• 78785-08-7 Methyl-6-O-benzyl-5-desoxy-5-C-methyl-3-O-(4-methylphenylsulfonyl)-L-idofuranosid 
• 78785-04-3 (3aR,5R,6S,6aR)-2,2-dimethyl-5-(prop-1-en-2-yl)tetrahydrofuro-[2,3-d][1,3]dioxol-6-yl4-methylbenzenesulfonate 
• 78785-29-2 Toluene-4-sulfonic acid (2R,3R,4R)-4,5-dihydroxy-2-((R)-2-hydroxy-1-methyl-ethyl)-tetrahydro-furan-3-yl ester 
• 78785-09-8 Methyl-6-O-benzyl-3,5-didesoxy-5-C-methyl-L-lyxo-hexofuranosid 
• 78785-02-1 6-Desoxy-1,2-O-isopropyliden-3-O-(4-methylphenylsulfonyl)-α-D-glucofuranose 

Relevant academic research and scientific papers

S–O Acetyl rearrangement in 6-thio-D-glucose derivatives

The solvolytic reaction of 1,2-O-isopropylidene-3,6-di-O-(p-toluene-sulphonyl)-α-D-glucofuranose (2), as well as that of 6-chloro-6-deoxy-1,2-O-isopropylidene-3-O-(p-toluenesulphonyl)-α-D-glucofuranose (3), in the presence of potassium thioacetate unexpec