168568-22-7Relevant academic research and scientific papers
Synthesis and glycosylating properties of ketopyranosyl donors
Heskamp,Veeneman,Van Der Marel,Van Boeckel,Van Boom
, p. 5657 - 5670 (2007/10/02)
The preparation of heptulopyranosyl donors 13-15, 28, 29 and 3-octulopyranosyl donors 34, 35, having a non-participating group at C-3 or C-4, respectively, is described. Glycosylations of various acceptors with these donors gave exclusively α-linked ketosides. On the other hand, condensation of 3-O-benzoyl heptulopyranosyl donor 19 with an acceptor furnished an anomeric mixture of ketodisaccharides.
