1686-50-6

Upstream product

• 76620-40-1 5-methyl-exo-6-phenethylbicyclo<3.1.0>hexan-2-one 

Downstream Products

• 124159-82-6 (+/-)-2c-benzoyloxy-4a-methyl-(4ar,10at)-1,2,3,4,4a,5,8,9,10,10a-decahydro-phenanthrene 
• 124159-82-6 (+/-)-2t-benzoyloxy-4a-methyl-(4ar,10ac)-1,2,3,4,4a,5,8,9,10,10a-decahydro-phenanthrene 
• 116603-48-6 (+/-)-2c-benzoyloxy-4a-methyl-(4ar,10ac)-1,2,3,4,4a,9,10,10a-octahydro-phenanthrene 
• 113092-00-5 (+/-)-7c-benzoyloxy-2ξ,3ξ;4a,10a-diepoxy-4b-methyl-(4aξ,4b#r,8at,10aξ)-tetradecahydro-phenanthrene 
• 116603-48-6 (+/-)-2t-benzoyloxy-4a-methyl-(4ar,10ac)-1,2,3,4,4a,9,10,10a-octahydro-phenanthrene 
• 116603-48-6 (+/-)-2c-benzoyloxy-4a-methyl-(4ar,10at)-1,2,3,4,4a,9,10,10a-octahydro-phenanthrene 

Relevant academic research and scientific papers

Lewis Acid Promoted Decomposition of Unsaturated α-Diazo Ketones. 3. Stereochemical Consequences of Polyolefinic Cyclizations Initiated by the α-Diazo Ketone Functionality

This report presents the stereochemical consequences of polyolefinic cyclizations initiated by Lewis acid decomposition of α-diazo ketones.Three diazo ketones (1, 2, and 5) were examined; each was found to undergo a nonstereospecific process leading eithe