168960-60-9Relevant academic research and scientific papers
Radical cyclization of highly functionalized precursors: Stereocontrol of ring closure of acyclic 1-substituted-2,4-dihydroxylated hex-5-enyl radicals
Roland, Arlenc,Durand, Thierry,Egron, David,Vidal, Jean-Pierre,Rossi, Jean-Claude
, p. 245 - 251 (2007/10/03)
Polysubstituted cyclopentane rings can be synthesized with good to high stereocontrol by radical cyclization using tributyltin hydride and a radical initiator, triethylborane-O2 in anhydrous xylene at room temperature. We have demonstrated that
Synthesis and determination of cis or trans isoprostane preciursors by a 1H NMR NOE study
Rondot, Benoit,Durand, Thierry,Vidal, Jean-Pierre,Girard, Jean-Pierre,Rossi, Jean-Claude
, p. 1589 - 1594 (2007/10/02)
Different isoprostane precursors have been synthesized from a 5-iodo-sugar via a radical cyclization initiated by azoisobutyronitrile (AIBN)-Et3B.The NOE 1H NMR experiment is a simple and efficient method for the determination of the relative functional c
