168977-44-4

Basic information

• Product Name: [Cu(As(C₆H₅)3)2(C₃H₅NS₂)Cl]
• CAS NO: 168977-44-4
• Molecular Weight: 830.688
• Mol File: 168977-44-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Cu(As(C₆H₅)3)2(C₃H₅NS₂)Cl](CAS DataBase Reference)
• NIST Chemistry Reference: [Cu(As(C₆H₅)3)2(C₃H₅NS₂)Cl](168977-44-4)
• EPA Substance Registry System: [Cu(As(C₆H₅)3)2(C₃H₅NS₂)Cl](168977-44-4)

Safety Data

• Hazardous Substances Data: 168977-44-4(Hazardous Substances Data)

Upstream product

• 134469-06-0 thiazolidine-2-thione 
• 603-32-7 triphenyl-arsane 

Relevant articles and documents

Synthesis and characterization of mixed ligand copper(I) complexes containing halides, triphenylarsine and N,N-dimethyl-N'-phenylthiourea (dmptH), N,N-dibutyl-N'-phenylthiourea (dbptH) or 1,3-thiazolidine-2-thione (tzdtH). The X-ray crystal structure of [Cu(PPh3)2(dmptH)Cl]

The arsine complexes [Cu(PPh3)2(LH)X] (LH=N,N-dimethyl-N'-phenylthiourea(dmptH), N,N-dibutyl-N'-phenylthiourea (dbptH) or 1,3-thiazolidine-2-th ione (tzdtH); X=Cl, Br, I) have been prepared and characterized on the basis of analytical, IR, electronic (UV-vis), (1)H NMR, conductivity and magnetic measurements. In all cases there is a distorted tetrahedral environment arround copper(I) and the ligands (LH) bind through thione sulphur atom to copper(I). We also report the crystal structure of complex [Cu(PPh3)2(dmptH)Cl] which shows that metal ion has a distorted tetrahedral geometry with bond lengths Cu-S=2.459(2), Cu-Cl=2.308(1), Cu-P(1)=2.305(1) and Cu-P(2)=2.313(1) ?. The NH is intramolecularly hydrogen bonded to Cl with a bond distance NH...Cl=2.31 ?.