168985-24-8Relevant articles and documents
1,2-cis-c-glycoside synthesis by samarium diiodide-promoted radical cyclizations
Skrydstrup, Troels,Mazeas, Daniel,Elmouchir, Mohamed,Doisneau, Gilles,Riche, Claude,Chiaroni, Angele,Beau, Jean-Marie
, p. 1342 - 1356 (2007/10/03)
The samarium diiodide reduction of glycosyl pyridyl sulfones bearing a silicon-tethered unsaturated group at the C2-OH position leads to the stereo-specific synthesis of 1,2-cis-C-glycosides in good yield after desilylation. These reactions proceed via an