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Bis-(triphenylphosphino)-cuprous borohydride, also known as Bis(triphenylphosphine)copper tetrahydroborate (CAS# 16903-61-0), is an organometallic compound that serves as a versatile catalyst in various chemical reactions. It is characterized by its unique structure, which includes a copper atom bonded to two triphenylphosphine ligands and a borohydride group. Bis-(triphenylphosphino)-cuprous borohydride is known for its ability to facilitate selective transformations in organic synthesis, making it a valuable tool in the field of chemistry.

16903-61-0

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16903-61-0 Usage

Uses

Used in Enantioseletive Radical Oxytrifluoromethylation:
Bis-(triphenylphosphino)-cuprous borohydride is used as a catalyst in the enantioseletive radical oxytrifluoromethylation of alkenes with alcohols. This application is significant because it allows for the selective introduction of the trifluoromethyl group, which is an important functional group in the pharmaceutical and agrochemical industries due to its unique properties and reactivity.
Used in the Preparation of Metal Cluster Complexes:
Bis-(triphenylphosphino)-cuprous borohydride is also utilized in the preparation of tungsten, ruthenium, and copper cluster complexes. These metal cluster complexes have a wide range of applications, including catalysis, materials science, and medicinal chemistry. The use of Bis-(triphenylphosphino)-cuprous borohydride as a catalyst in their synthesis contributes to the development of new and improved materials with potential applications in various industries.

Check Digit Verification of cas no

The CAS Registry Mumber 16903-61-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,6,9,0 and 3 respectively; the second part has 2 digits, 6 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 16903-61:
(7*1)+(6*6)+(5*9)+(4*0)+(3*3)+(2*6)+(1*1)=110
110 % 10 = 0
So 16903-61-0 is a valid CAS Registry Number.
InChI:InChI=1/C7H15NO4/c1-7(2,3)11-12-8-5-4-6(9)10/h8H,4-5H2,1-3H3,(H,9,10)

16903-61-0 Well-known Company Product Price

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  • TCI America

  • (B1139)  Bis(triphenylphosphine)copper Tetrahydroborate  >90.0%(T)

  • 16903-61-0

  • 5g

  • 290.00CNY

  • Detail
  • Alfa Aesar

  • (A13730)  Bis(triphenylphosphine)copper(I) borohydride   

  • 16903-61-0

  • 5g

  • 257.0CNY

  • Detail
  • Alfa Aesar

  • (A13730)  Bis(triphenylphosphine)copper(I) borohydride   

  • 16903-61-0

  • 25g

  • 961.0CNY

  • Detail
  • Alfa Aesar

  • (A13730)  Bis(triphenylphosphine)copper(I) borohydride   

  • 16903-61-0

  • 100g

  • 2736.0CNY

  • Detail

16903-61-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name Bis(triphenylphosphine)copper Tetrahydroborate

1.2 Other means of identification

Product number -
Other names Bis-(triphenylphosphino)-cuprous borohydride

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:16903-61-0 SDS

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