169137-92-2Relevant academic research and scientific papers
New versatile fluorinated chiral building blocks: Synthesis and reactivity of optically pure α-(fluoroalkyl)-β-sulfinylenamines
Arnone, Alberto,Bravo, Pierfrancesco,Capelli, Silvia,Fronza, Giovanni,Meille, Stefano V.,Zanda, Matteo,Cavicchio, Giancarlo,Crucianelli, Marcello
, p. 3375 - 3387 (2007/10/03)
Efficient synthesis of optically pure α-(fluoroalkyl)-β-sulfinyl enamines has been achieved by aza-Wittig reaction of triphenyliminophosphoranes with the corresponding α-fluorinated-α'-sulfinyl ketones. The title compounds 3,4 showed an overwhelming prefe
Stereoselective synthesis of optically pure γ-fluoro-βenaminosulfoxides and reduction to γ-fluoro-βaminosulfoxides
Bravo, Pierfrancesco
, p. 3043 - 3046 (2007/10/02)
The aza-Wittig reaction of phospha-λ5-azenes with optically pure γ-fluorosubstituted β-ketosulfoxides leads to the corresponding β-enaminosulfoxides, which were easily isolated in diastereomerically pure form. The stereoselective reduction of t
