169176-65-2

Upstream product

• 169176-61-8 (2S,4S)-3-<2-Azido-2-(4-methoxyphenyl)-1-oxoethyl>-4-(phenylmethyl)-2-oxazolidinone 
• 169176-57-2 N--L-(4-methoxyphenyl)glycinyl>-D-(3-hydroxy-4-methoxyphenyl)glycine ethyl ester 
• 169176-62-9 (2S,4S)-3-<2-<<(Phenylmethoxy)carbonyl>amino>-2-(4-methoxyphenyl)-1-oxoethyl>-4-(phenylmethyl)-2-oxazolidinone 
• 169176-59-4 (2R)-2-Azido-2-<(3-(benzyloxy)-4-methoxy)phenyl>acetic acid ethyl ester 
• 169273-94-3 (S)-(N-benzyloxycarbonyl)-p-methoxyphenylglycine 
• 143589-97-3 (4S)-3-<2-(4-Methoxyphenyl)-1-oxoethyl>-4-(phenylmethyl)-2-oxazolidinone 
• 126702-34-9 C₁₄H₁₈O₄ 
• 169176-60-7 D-<(3-Hydroxy-4-methoxy)phenyl>glycine ethyl ester 
• 159579-64-3 (2R)-2-Azido-2-<(3-(benzyloxy)-4-methoxy)phenyl>acetic acid 
• 501-53-1 benzyl chloroformate 
• 104-01-8 4-Methoxyphenylacetic acid 
• 169176-58-3 (2R)-3-<4-<2-<<(1,1-Dimethylethoxy)carbonyl>amino>-3-oxo-3-(2-bromoethoxy)propyl>phenoxy>-4-methoxy-N--L-(4-methoxyphenyl)glycinyl>-D-phenylglycine ethyl ester 

Downstream Products

• 169176-66-3 (R)-4-<2-Methoxy-5-<1--L-(4-methoxyphenyl)glycinyl>amino>-2-ethoxy-2-oxoethyl>phenoxy>-N-<(1,1-dimethylethoxy)carbonyl>-D-phenylalanine 
• 169176-69-6 (1R,2R)-amino>-3-hydroxy-3-oxopropyl>phenoxy>-4-methoxyphenyl>-2-ethoxy-2-oxoethyl>amino>-(S)-(4-methoxyphenyl)glycine 
• 169176-67-4 (R)-4-<3-<1--L-(4-methoxyphenyl)glycinyl>amino>-2-(ethoxycarbonyl)ethyl>-4-methoxyphenoxy>-N-<(1,1-dimethylethoxy)carbonyl>-D-phenylalanine pentafluorophenyl ester 

Relevant academic research and scientific papers

Synthesis of a 16-Membered Cyclic Peptide Model of the BCF Rings of Ristocetin A Using Arene-Ruthenium Chemistry Coupled with Cycloamidation

A convergent synthetic approach to the cyclic peptide 4, which is a model for the B/C/F ring system of ristocetin B, is described.A key reaction is the coupling of the phenolic dipeptide 5, constructed from arylglycine subunits, with the chlorophenylalanine-RuCp cationic complex 6, followed by demetalation of the product to give the diaryl ether 7, without epimerization at any of the amino acid residues.Deprotection of 7 followed by cycloamidation affords the target molecule 4, produced as a mixture of atropdiastereomers which were separated and characterized by NMR spectroscopy.