16933-43-0

Basic information

• Product Name: (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl diphenylphosphinate
• Synonyms: (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl diphenylphosphinate
• CAS NO: 16933-43-0
• Molecular Weight: 356.445
• Mol File: 16933-43-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl diphenylphosphinate(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl diphenylphosphinate(16933-43-0)
• EPA Substance Registry System: (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl diphenylphosphinate(16933-43-0)

Safety Data

• Hazardous Substances Data: 16933-43-0(Hazardous Substances Data)

Upstream product

• 2216-51-5 (-)-menthol 
• 1499-21-4 Diphenylphosphinic chloride 
• 4559-70-0 Diphenylphosphine oxide 

Downstream Products

• 5994-87-6 diphenylphosphinamide 

Relevant articles and documents

Electrochemical Dehydrogenative Coupling of Alcohols with Hydrogen Phosphoryl Compounds: A Green Protocol for P?O Bond Formation

This study reports the environment-friendly electrochemical transformation of structurally diverse phosphorus compounds and alcohol into phosphonates in the presence of ammonium iodide as electrolyte and redox catalyst in acetonitrile at ambient temperature. This method for P?O bond formation exhibits remarkable features, such as transition metal- and oxidant-free conditions. A reliable mechanism is proposed after control and cyclic voltammetry experiments. (Figure presented.).

Iron-catalyzed clean dehydrogenative coupling of alcohols with P(O)-H compounds: A new protocol for ROH phosphorylation

An efficient oxygen-phosphoryl bond-forming reaction via iron-catalyzed cross dehydrogenative coupling has been developed. This transformation proceeds efficiently under oxidant- and halide-free reaction conditions with H2 liberation, and represents a straightforward method to prepare valuable organophosphoryl compounds from the readily available alcohols and P(O)-H compounds.

Iridium(III)-Catalyzed C H Amidation of Arylphosphoryls Leading to a P-Stereogenic Center

Direct C H amidation of arylphosphoryl compounds has been developed by using an IrIIIcatalyst system under mild conditions. A wide range of substrates could be employed with high functional-group tolerance. This procedure was successfully applied for the first time to the asymmetric reaction giving rise to a P-chirogenic center with a high diastereomeric ratio of up to 19:1 (90 % de).