169532-71-2

Upstream product

• 169396-37-6 (4R,5S)-methyl 5-(but-3-enyl)-2,2-dimethyl-1,3-dioxolane-4-carboxylate 
• 169396-39-8 2-<(4R,5S)-5-(but-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl>propan-2-yl nitrate 
• 169396-38-7 2-<(4R,5S)-5-(but-3-enyl)-2,2-dimethyl-1,3-dioxolan-4-yl>propan-2-ol 
• 67844-13-7 methyl (4R,5S)-5-(hydroxymethyl)-2,2-dimethyl-1,3-dioxolane-4-carboxylate 
• 20913-05-7 (Benzoylmethylene)triphenylphosphorane 
• 169396-40-1 2-<(4R,5S)-5-(2-formylethyl)-2,2-dimethyl-1,3-dioxolan-4-yl>propan-2-yl nitrate 

Relevant academic research and scientific papers

Stereocontrol in cyclisation of dioxolanyl radicals

Appropriate nitrate esters are cleaved under photolytic or thermal (tributyltin radical) conditions to yield dioxolanyl radicals which undergo stereoselective cyclisation to heterocyclic products.The X-ray crystallographic structures for compounds 30a and 35 are reported.