169557-87-3Relevant articles and documents
Synthesis and scalable conversion of L-iduronamides to heparin-related Di- and tetrasaccharides
Hansen, Steen U.,Miller, Gavin J.,Barath, Marek,Broberg, Karl R.,Avizienyte, Egle,Helliwell, Madeleine,Raftery, James,Jayson, Gordon C.,Gardiner, John M.
, p. 7823 - 7843 (2013/01/15)
A diastereomerically pure cyanohydrin, preparable on kilogram scale, is efficiently converted in one step into a novel L-iduronamide. A new regioselective acylation of this iduronamide and a new mild amide hydrolysis method mediated by amyl nitrite enable
2-Deoxy-2-trichloroacetamido-D-glucopyranose derivatives in oligosaccharide synthesis: from hyalouronic acid to chondroitin 4-sulfate trisaccharides
Coutant, Caroline,Jacquinet, Jean-Claude
, p. 1573 - 1582 (2007/10/02)
Suitably protected derivatives of phenyl 2-deoxy-1-thio-2-trichloroacetamido-β-D-glucopyranoside, 6, 15 and 16, a new class of glycosyl donors, were tested in the reaction with sugar acceptors of low reactivity (i.e., the methyl uronate 2).This methodolog