16958-43-3Relevant articles and documents
Stereocontrol with phosphine oxides: Synthesis of optically active cyclopropyl ketones
Nelson, Adam,Warren, Stuart
, p. 3425 - 3433 (2007/10/03)
Treatment of -keto y'-hydroxy phosphine oxides, or silylated hemiacetal derivatives of these compounds, with potassium /e/7-butoxide in /e/7-butyl alcohol leads to the formation of cyclopropyl ketones. The synthesis of optically active 1, 2-di- and 1, 2,
Chelation Control in the Hydroformylation of Terminal Alkenes
Jackson, W. Roy,Perlmutter, Patrick,Suh, Guem-Hee
, p. 724 - 725 (2007/10/02)
Hydroformylation of phosphine-bearing terminal alkenes can lead to a complete reversal of regioselection to that observed for simpler alkenes.