16980-14-6Relevant articles and documents
Total synthesis of chlorophyll c fossils and related petroporphyrins
Bauder,Ocampo,Callot
, p. 2537 - 2540 (1991)
The total synthesis of a series of petroporphyrins related to chlorophyll c is described. These compounds have in common, fused to the porphyrin macrocycle, a methylcyclopentane ring which was obtained via cyclization of an isopropenyl group.
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Sugihara,McGee
, p. 795,798 (1957)
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Total synthesis of the porphyrin mineral abelsonite and related petroporphyrins with five-membered exocyclic rings
Zhang, Bo,Lash, Timothy D.
, p. 7253 - 7256 (2007/10/03)
A reliable synthesis of porphyrins with five-membered exocyclic rings from b-bilenes has been developed. This methodology has been applied to the first total synthesis of the porphyrin mineral abelsonite, as well as the widespread petroporphyrin deoxophyl
A novel and convenient conversion of chlorins to phytoporphyrins during the modification of chlorophyll derivatives
Ma, Lifu,Dolphin, David
, p. 7791 - 7794 (2007/10/02)
Chlorophyll derivatives 2a, 2b, 2c and 3 have been readily converted to their corresponding phytoporphyrins 5a, 5b, 5c in excellent yields using benzoyl chloride in DMF. This method affords a new and efficient route to prepare monovinyl porphyrins which can be used as intermediates for the further preparation of chlorophyll related petroporphyrins and regiochemically pure benzoporphyrin derivatives for use in photodynamic therapy.