169888-75-9Relevant academic research and scientific papers
2-Azanorbornane-based amine organocatalyst for enantioselective aldol reaction of isatins with ketones
Ogasawara, Ayumi,Subba Reddy,Seki, Chigusa,Okuyama, Yuko,Uwai, Koji,Tokiwa, Michio,Takeshita, Mitsuhiro,Nakano, Hiroto
, p. 1062 - 1068 (2016/10/11)
Optically active 2-azanorbornane-based organocatalysts were designed and synthesized, and the catalytic activity of these catalysts in enantioselective aldol reactions of isatins with ketones was investigated. Among these catalysts, 2-azanorbornylmethanol
Enantioselective epoxidation of α,β-enones promoted by (1R,3S,4S)-2-azanorbornyl-3-methanol as an organocatalyst
Lu, Jun,Xu, Yun-He,Liu, Feng,Loh, Teck-Peng
supporting information; scheme or table, p. 6007 - 6008 (2009/04/04)
(1R,3S,4S)-2-Azanorbornyl-3-methanol was synthesized form (R)-1-phenylethylamine and used as a catalyst for the enantioselective epoxidation of α,β-enones to afford the corresponding epoxides in good yields and high enantioselectivities at room temperature.
Enantioselective addition of diethylzinc to aldehydes using 2-azanorbornylmethanols and 2-azanorbornylmethanethiol as a catalyst
Nakano, Hiroto,Kumagai, Noriyuki,Matsuzaki, Hisao,Kabuto, Chizuko,Hongo, Hiroshi
, p. 1391 - 1401 (2007/10/03)
Optically active 2-azanorbornylmethanols and 2-azanorbomylmethanethiol were prepared from ethyl (1S,3S,4R)-2-[(R)-1-phenylethyl]-2-azabicyclo[2.2.1]hept-5-ene- 3-carboxylate and catalyzed the enantioselective addition of diethylzine to aldehydes to give o
Synthesis of new chiral catalysts, N-alkyl-2-azanorbornyl-methanols, for the enantioselective addition of diethylzinc to arylaldehydes
Nakano,Kumagai,Kabuto,Matsuzaki,Hongo
, p. 1233 - 1236 (2007/10/02)
New chiral ligands, 2-azanorbornylmethanols, were prepared and catalyzed the addition of diethylzinc to arylaldehydes to furnish secondary alcohols in up to 92% ee.
