169897-60-3

Upstream product

• 2071-20-7 bis-diphenylphosphinomethane 

Downstream Products

• 121596-59-6 bis(diphenylphosphino)methane(chloro)(pentamethylcyclopentadienyl)rhodium(III) chloride 
• 169897-79-4 (C₅(CH₃)5)RhCl((C₆H₅)2P(S)CH₂P(S)(C₆H₅)2)⁽¹⁺⁾*ClO₄^(1-)=[(C₅(CH₃)5)RhCl((C₆H₅)2P(S)CH₂P(S)(C₆H₅)2)]ClO₄ 
• 169897-77-2 (C₅(CH₃)5)RhCl((C₆H₅)2PCH₂P(Se)(C₆H₅)2)⁽¹⁺⁾*ClO₄^(1-)=[(C₅(CH₃)5)RhCl((C₆H₅)2PCH₂P(Se)(C₆H₅)2)]ClO₄ 
• 169897-67-0 (C₅(CH₃)5)RhCl((C₆H₅)2PCH₂P(Se)(C₆H₅)2)⁽¹⁺⁾*Cl^(1-)=[(C₅(CH₃)5)RhCl((C₆H₅)2PCH₂P(Se)(C₆H₅)2)]Cl 
• 169897-64-7 [(C₅(CH₃)5)RhCl₂((C₆H₅)2PCH₂P(S)(C₆H₅)2)] 
• 169897-75-0 (C₅(CH₃)5)RhCl((C₆H₅)2PCH₂P(C₆H₅)2)⁽¹⁺⁾*ClO₄^(1-)=[(C₅(CH₃)5)RhCl((C₆H₅)2PCH₂P(C₆H₅)2)]ClO₄ 

Relevant academic research and scientific papers

Bis(diphenylphosphino)methane and its sulphide or selenide derivatives as ligands in ruthenium(II) and rhodium(III) complexes: crystal structureof [(η6C6Me6)Ru{SPPh2)2CH}]ClO4

Reaction of complexes [(η6C6Me6)RuCl2]2 and [(η5C5Me5)RhCl2]2 with the ligands L=Ph2PCH2PPh2 (dppm) or Ph2PCH2P(Se)Ph2 in benzene solutions led to neutral complexes with the general formula [(ring)MCl2(η1L)]. The reactivity of the uncoordinated P atom of