Methanesulfonato(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine(2'-amino-1,1'-biphenyl-2-yl)palladium(II), also known as Josiphos SL-J009-1 Pd G3, is a modified G3 precatalyst (G3′) synthesized by Buchwald and coworkers. It is a versatile catalyst with a long life in solution and is readily soluble in various organic solvents. It has been used in various C-N bond forming reactions.
1702311-34-9
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Basic information
- Product Name: Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
- Synonyms: Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II),[Josiphos Palladacycle Gen. 3]
- CAS NO:1702311-34-9
- Molecular Formula: C45H66FeNO3P2PdS 10*-
- Molecular Weight: 925.287962
- EINECS: N/A
- Product Categories: N/A
- Mol File: 1702311-34-9.mol
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Chemical Properties
- Melting Point: N/A
- Boiling Point: N/A
- Flash Point: N/A
- Appearance: red-orange/solid
- Density: N/A
- Refractive Index: N/A
- Storage Temp.: N/A
- Solubility: N/A
- CAS DataBase Reference: Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)(CAS DataBase Reference)
- NIST Chemistry Reference: Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)(1702311-34-9)
- EPA Substance Registry System: Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)(1702311-34-9)
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Safety Data
- Hazard Codes: N/A
- Statements: N/A
- Safety Statements: N/A
- WGK Germany:
- RTECS:
- HazardClass: N/A
- PackingGroup: N/A
- Hazardous Substances Data: 1702311-34-9(Hazardous Substances Data)
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1702311-34-9 Usage
Uses
Used in Pharmaceutical Industry:Methanesulfonato(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine(2'-amino-1,1'-biphenyl-2-yl)palladium(II) is used as a catalyst for various cross-coupling reactions, which are essential for the synthesis of complex organic molecules, including pharmaceutical compounds.
Used in Chemical Industry:
Methanesulfonato(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine(2'-amino-1,1'-biphenyl-2-yl)palladium(II) is used as a catalyst for C-N bond forming reactions, which are crucial for the synthesis of various organic compounds, including agrochemicals and specialty chemicals.
Used in Research and Development:
Methanesulfonato(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine(2'-amino-1,1'-biphenyl-2-yl)palladium(II) is used as a catalyst in research and development for the synthesis of new compounds and the optimization of existing synthetic routes.
Reaction
Catalyst used for C-O coupling reactions between electron-deficient phenols and functionalized heteroaryl chlorides.Check Digit Verification of cas no
The CAS Registry Mumber 1702311-34-9 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,7,0,2,3,1 and 1 respectively; the second part has 2 digits, 3 and 4 respectively.Calculate Digit Verification of CAS Registry Number 1702311-34:
(9*1)+(8*7)+(7*0)+(6*2)+(5*3)+(4*1)+(3*1)+(2*3)+(1*4)=109
109 % 10 = 9
So 1702311-34-9 is a valid CAS Registry Number.
1702311-34-9Upstream product
1702311-34-9Downstream Products
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Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
