1704-69-4

Basic information

• Product Name: Morpholine, 2,2,3,3,5,5,6,6-octafluoro-4-(heptafluoropropyl)-
• CAS NO: 1704-69-4
• Molecular Formula: C7F15NO
• Molecular Weight: 399.059
• Mol File: 1704-69-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Morpholine, 2,2,3,3,5,5,6,6-octafluoro-4-(heptafluoropropyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Morpholine, 2,2,3,3,5,5,6,6-octafluoro-4-(heptafluoropropyl)-(1704-69-4)
• EPA Substance Registry System: Morpholine, 2,2,3,3,5,5,6,6-octafluoro-4-(heptafluoropropyl)-(1704-69-4)

Safety Data

• Hazardous Substances Data: 1704-69-4(Hazardous Substances Data)

Usage

General Description

Morpholine, 2,2,3,3,5,5,6,6-octafluoro-4-(heptafluoropropyl)-, also known as 2,2,3,3,5,5,6,6-octafluoro-4-(heptafluoropropyl)morpholine, is a chemical compound commonly used as a solvent, intermediate, and additive in various industries. It is a colorless liquid with a faint odor and is highly stable under normal conditions. Morpholine, 2,2,3,3,5,5,6,6-octafluoro-4-(heptafluoropropyl)- is mainly used as a key ingredient in the production of specialty chemicals, pharmaceuticals, and polymers. It is also utilized in the manufacturing of surfactants, resins, and coatings. Additionally, it is known for its low toxicity and is considered safe for handling when proper precautions are taken.

Upstream product

• 7357-67-7 4-(3-chloropropyl)morpholine 
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• 20120-26-7 (2-methyl-3-morpholin-4-yl)propionic acid methyl ester 
• 5471-53-4 methyl 4-morpholinobutanoate 
• 32418-63-6 ethyl 2-morpholinobutyrate 

Relevant articles and documents

ELECTROCHEMICAL FLUORINATION OF N-CHLOROALKYL-SUBSTITUTED CYCLIC AMINES

The electrochemical fluorination of such N-chloroalkyl substituted cyclic amines as N-chloromethylpyrrolidine (1), N-(3-chloropropyl)pyrrolidine (2), N-chloromethylpiperidine (3), N-(2-chloroethyl)piperidine (4), N-(3-chloropropyl)piperidine (5), N-chloromethylmorpholine (6), N-(3-chloropropyl)morpholine (7), N-(2-chloroallyl)morpholine (8) has been conducted.Except in the cases of the N-chloromethyl-substituted ones (1,3 and 6), the corresponding chlorine-retaining-perfluoroamines were obteined in a yield of 5 - 20 percent together with perfluorinated ones (Yield = 20 - 60 percent).Neither chlorine-retaining amines nor perfluorinated amines, both of which having the original skeleton, was produced from fluorinations of 1, 3 and 6 in an appreciable yield.The spectroscopic data and physical properties of newly synthesized perfluoro-N-chloroalkyl-substituted cyclic amines are presented.

The electrochemical fluorination of N-containing carboxylic acids (Part 4). Fluorination of methyl 3-dialkylamino-isobutyrates and methyl 3-dialkylamino-n-butyrates

Several methyl esters of 3-dialkylamino-substituted n- and isobutyric acids have been subjected to electrochemical fluorination to give the corresponding perfluoroacid fluorides.Dimethyl, diethyl, pyrrolidino, morpholino, piperidino and N-methylpiperazino groups were investigated as dialkylamino substituents.The structure/yield relationship was evaluated both in terms of the structure of the acid and the kind of amino group, respectively.Better yields of perfluoroacid fluorides were obtained from methyl esters having isobutyric acid skeletons than those having n-butyric acid groups, and from the acids containing cyclic amino groups than those containing acyclic ones.