170463-49-7Relevant academic research and scientific papers
Sulfide ion transfer from a vicinal dithiolate. A new route for the synthesis of mesocyclic trithiaethers
Qu, Wenchao,Rorabacher, David B.,Taschner, Michael J.
, p. 8057 - 8060 (2007/10/03)
Four mesocyclic and one macrocyclic trithiaethers have been synthesized using a sulfide ion transfer from a vicinal dithiolate. The mechanism of the sulfide ion transfer is discussed. An improved method for synthesizing 2-hydroxymethyl-1,4,8,11-tetrathiacyclotetradecane is also reported.
Macrocyclic dithiomaleonitrile derivatives containing sulfur and nitrogen heteroatoms
Lange, Steven J.,Sibert, John W.,Stern, Charlotte L.,Barrett,Hoffman, Brian M.
, p. 8175 - 8188 (2007/10/02)
A general synthetic method for incorporation of the dithiomaleonitrile unit into macrocycles containing sulfur, oxygen and nitrogen heteroatoms is presented along with the single-crystal X-ray structures of the thiacrowns. In addition to being new ligands, these macrocycles are direct precursors to peripherally crown functionalized porphyrazines capable of coordinating multiple metal ions.
