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17057-95-3

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17057-95-3 Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 83, p. 1751, 1961 DOI: 10.1021/ja01468a045

Check Digit Verification of cas no

The CAS Registry Mumber 17057-95-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,7,0,5 and 7 respectively; the second part has 2 digits, 9 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 17057-95:
(7*1)+(6*7)+(5*0)+(4*5)+(3*7)+(2*9)+(1*5)=113
113 % 10 = 3
So 17057-95-3 is a valid CAS Registry Number.
InChI:InChI=1/C13H14/c1-3-7-12-10(5-1)9-11-6-2-4-8-13(11)12/h1,3,5,7H,2,4,6,8-9H2

17057-95-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 2,3,4,9-tetrahydro-1H-fluorene

1.2 Other means of identification

Product number -
Other names 2,3,4,9-tetrahydro-1H-fluoren

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:17057-95-3 SDS

17057-95-3Relevant articles and documents

Silicon-Modified Metal-Ammonia Reduction of Fluorene

Smith, W. Kimmer,Hardin, Julie N.,Rabideau, Peter W.

, p. 5301 - 5302 (1990)

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Easy Access to Versatile Catalytic Systems for C?H Activation and Reductive Amination Based on Tetrahydrofluorenyl Rhodium(III) Complexes

Kharitonov, Vladimir B.,Runikhina, Sofiya A.,Nelyubina, Yulia V.,Muratov, Dmitry V.,Chusov, Denis,Loginov, Dmitry A.

supporting information, p. 10903 - 10912 (2021/06/28)

On the basis of the 1,2,3,4-tetrahydrofluorenyl ligand, a simple approach was developed to new effective rhodium catalysts for the construction of C?C and C?N bonds. The halide compounds [(η5-tetrahydrofluorenyl)RhX2]2 (2

Rhodium(II)- or Copper(I)-Catalyzed Formal Intramolecular Carbene Insertion into Vinylic C(sp2)?H Bonds: Access to Substituted 1H-Indenes

Zhou, Qi,Li, Shichao,Zhang, Yan,Wang, Jianbo

supporting information, p. 16013 - 16017 (2017/11/27)

A rhodium(II)- or copper(I)-catalyzed formal intramolecular carbene insertion into vinylic C(sp2)?H bonds is reported herein. This method provides straightforward access to 1H-indenes with high efficiency and excellent functional-group compatibility. Mechanistically, the reaction is proposed to involve the following sequence: metal carbene formation, intramolecular nucleophilic addition of the double bond to the electron-deficient carbene carbon atom, dearomatization, and finally a 1,5-H shift.

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