17059-55-1Relevant articles and documents
Regioselective synthesis of substituted 1-methyl- and 2-methylnaphthalenes
Yadav, K. Mallik,Mohanta, Pramod K.,Ila, Hiriyakkanavar,Junjappa, Hiriyakkanavar
, p. 14049 - 14056 (1996)
Regiospecifically substituted 1-methyl- and 2-methylnaphthalenes, 5-methyl- and 6-methyl-1,2,3,4-tetrahydroanthracenes have been synthesized in good yields through 1,2-addition of the corresponding α-lithio- o- or m-xylenes onto α-oxoketene dithioacetals or their dihydro derivatives followed by cyclodehydration of the resulting carbinols in the presence of borontrifluoride etherate.
Construction of polyaromatics via photocyclization of 2-(fur-3-yl) ethenylarenes, using a 3-furyl group as an isopropenyl equivalent synthon
Chen, Ying-Zhe,Ni, Ching-Wen,Teng, Fu-Lin,Ding, Yi-Shun,Lee, Tunng-Hsien,Ho, Jinn-Hsuan
, p. 1748 - 1762 (2014/03/21)
The construction of different types of substituted arenes was demonstrated through the photocyclization of 2-(fur-3-yl)ethenylarenes using a 3-furyl group as an isopropenyl equivalent synthon in the photocyclization reaction. The furan portion of the photocyclization intermediate could be fragmented via a base-induced elimination reaction to yield a series of substituted polyaromatics, including naphthalene, benzofuran, benzothiophene, phenanthrene, phenalene, acenaphthene, and triphenylene. Using different reagents, this method made it possible to introduce methyl or 2-hydroxyethyl groups as substituents at specific positions in these arenes.