17060-07-0

Basic information

• Product Name: 1,2-DICHLOROETHANE-D4
• Synonyms: 1,2-DICHLOROETHANE-D4;DEUTERO-1,2-DICHLOROETHANE;ETHYLENE-D4 DICHLORIDE;ETHYLENE-D4 CHLORIDE;1,2-DICHLOROETHANE-D4, 1000MG, NEAT;1,2 DICHLOROETHANE-D4, 1X1ML, MEOH, 2000 UG/ML;1,2-DICHLOROETHANE-D4, 99 ATOM % D;Ethane-1,1,2,2-d4, 1,2-dichloro-
• CAS NO: 17060-07-0
• Molecular Formula: C₂H₄Cl₂
• Molecular Weight: 102.98
• Product Categories: 600 Series Wastewater Methods;Alpha Sort;D;DAlphabetic;DIA - DICEPA;Method 624;Volatiles/ Semivolatiles
• Mol File: 17060-07-0.mol
• Article Data: 2

Chemical Properties

• Melting Point: −35 °C(lit.)
• Boiling Point: 83 °C(lit.)
• Flash Point: 60 °F
• Appearance: /Liquid
• Density: 1.307 g/mL at 25 °C(lit.)
• Refractive Index: n20/D 1.443(lit.)
• Storage Temp.: 2-8°C
• Water Solubility: Partially miscible with water.
• CAS DataBase Reference: 1,2-DICHLOROETHANE-D4(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-DICHLOROETHANE-D4(17060-07-0)
• EPA Substance Registry System: 1,2-DICHLOROETHANE-D4(17060-07-0)

Safety Data

• Hazard Codes: F,T
• Statements: 45-11-22-36/37/38-39/23/24/25-23/24/25
• Safety Statements: 53-45-36/37-16
• RIDADR: UN 1184 3/PG 2
• WGK Germany: 3
• HazardClass: 3
• PackingGroup: II
• Hazardous Substances Data: 17060-07-0(Hazardous Substances Data)

Usage

Uses

Different sources of media describe the Uses of 17060-07-0 differently. You can refer to the following data:
1. 1,2-Dichloroethane-d4 is widely used as a solvent for NMR analysis, and in the synthesis of poly(ethylene-d4 oxide) as a chain termination reagent.
2. 1,2-Dichloroethane-d4 may be used:As a NMR solvent.As a surrogate standard during the analysis of volatile organic compounds (VOC) in water by gas chromatography-mass spectrometry (GC-MS).As a chain termination reagent in the synthesis of poly(ethylene-d4 oxide).

General Description

1,2-Dichloroethane-d4 is 1,2-dichloroethane with all the hydrogen atoms replaced by deuterium. Its synthesis and structure elucidation by neutron diffraction measurements has been reported.

Upstream product

• 683-73-8 Ethylene-d4 
• 2219-51-4 [1,1,2,2-⁽²⁾H₄]ethane-1,2-diol 
• 19199-91-8 chloro-pentadeuterio-ethane 

Downstream Products

• 167301-26-0 1,2-bis(phenylthio)ethane-d4 
• 1252995-10-0 2-(2-chloro-d4-ethyl)isoindoline-1,3-dione 
• 15393-14-3 cis-[bis(dimethylphenylphosphane)dichlroplatinum(II)] 

Related news

Experimental and theoretical studies of the reactions of chlorine atoms with 1,2-dichloroethane and 1,2-DICHLOROETHANE-D4 (cas 17060-07-0) in the gas phase. The kinetics of hydrogen atom abstraction from the –CH2Cl group in chloroethane and 1,2-dichloroethane08/09/2019

The rate constant for H-abstraction (kH) from CH2ClCH2Cl and D-abstraction (kD) from CD2ClCD2Cl by chlorine atoms is described by the expressions: kH = (1.99 ± 0.12) × 10−11 exp(−777 ± 23/T) cm3 molecule−1 s−1 and kD = (1.73 ± 0.12) × 10−11 exp(−1148 ± 16/T) cm3 molecule−1 s−1. The experim...detailed

Relevant articles and documents

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Photochlorination of Chloroethane and Chloroethane-d5

The hydrogen/deuterium abstraction from C2H5Cl and C2D5Cl by ground-state chlorine atoms has been investigated between 8 and 94 deg C.Results from the internal competition in chloroethane and chloroethane-d5 combined with the results of external competition with CH4 as the reference reaction have yielded rate constant data for the following reactions: CH3CH2Cl + Cl -> CH3CHCl + HCl, k2s; CH3CH2Cl + Cl -> CH2CH2Cl + HCl, k2p; CD3CD2Cl + Cl -> CD3CDCl + DCl, k2s,D; CD3CDCl + Cl -> CD2CD2Cl + DCl, k2p,D.The temperature dependence of the rate constants (cm3s-1) is given by k2s = (1.43 +/- 0.29) X 1E-11 exp, k2p = (1.35 +/- 0.28) X 1E-11 exp, k2s,D = (0.72 +/- 0.14) X 1E-11 exp , and k2p,D = (0.60 +/- 0.12) X 1E-11 exp.The results confirm the general trend of chlorine atom attack being faster at the substituted carbon atom.Kinetic isotope effects for the abstraction of primary and secondary hydrogen are kH/kD = 5.8 and 2.0 at 298 K, respectively.The magnitude of these relatively weak isotope effects agrees with expectations based on other exothermic chlorination reactions and suggests that in the temperature range of the investigation tunneling does not play an important role.