170647-33-3Relevant academic research and scientific papers
Optically active tertiary phosphine compound, transition metal complex comprising the same as ligand and process for preparing optically active organic silicon compound using said transition metal complex
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, (2008/06/13)
A tertiary phosphine compound of the formula (1): STR1 in which R1 and R1' are hydrogen atoms or together form --CH=CH--CH=CH--; R2 and R3 together form a group of the formula (a): STR2 in which --.circle-solid. represent a bond to be bonded to the R3 group, and --? represents a bond to be bonded to the R2 group when R1 and R1 ' together form --CH=CH--CH=CH--, or when R1 is a hydrogen atom, R2 and R3 together form --CH=CH--CH=CH-- or R2 is a hydrogen atom and R3 is a substituted or unsubstituted alkyl group, or a substituted or unsubstituted phenyl group; A1 is a 3-trifluoromethylphenyl group or a 3,5-bis(trifluoromethyl)phenyl group when R1 is a hydrogen atom and R2 and R3 together form --CH=CH--CH=CH--, or a substituted or unsubstituted phenyl group when R1 is not a hydrogen atom or when R2 and R3 do not together form --CH=CH--CH=CH--.
