170700-65-9Relevant academic research and scientific papers
Synthesis and reactivity of complexes 2a-c, their involvement as catalyst precursors for regioselective allylic substitution reactions and related [Ru(Cp*)Cl(Ph2POMe)(RCHCHCH2)] [PF6] η3-allyl ruthenium(IV)inter
Demerseman, Bernard,Renaud, Jean-Luc,Toupet, Loic,Hubert, Claudie,Bruneau, Christian
, p. 1371 - 1380 (2007/10/03)
The synthesis of the new complexes [Ru(Cp*)(L)(MeCN) 2]-[PF6] (L = Ph2POMe or Ph2P-o- tolyl) and {Ru(Cp*)-[Ph2PCH2C(tBu)=O](MeCN)}[PF 6] (2a-c) is achieved starting from [Ru(Cp*)
Regio- and enantioselective allylic alkylation of an unsymmetrical substrate: A working model
Trost,Toste
, p. 4545 - 4554 (2007/10/03)
The evolution of a model for understanding asymmetric allylic alkylations catalyzed by palladium with the use of ligands derived from chiral diamines and 2-diphenylphosphinobenzoic acid provides a basis for attacking the problem of regio- and enantioselec
