17071-54-4

Usage

InChI:InChI=1/C14H30O/c1-3-5-7-9-10-12-14-15-13-11-8-6-4-2/h3-14H2,1-2H3

Upstream product

• 111-25-1 1-bromo-hexane 
• 17158-60-0 sodium octanolate 
• 111-87-5 octanol 
• 638-45-9 1-Iodohexane 
• 14246-16-3 trimethyl(oct-1-yloxy)silane 
• 66-25-1 hexanal 
• 71-36-3 butan-1-ol 
• 111-27-3 hexan-1-ol 
• 1117-55-1 n-hexyl octanoate 
• 124-13-0 Octanal 

Relevant academic research and scientific papers

Continuous-Flow Reductive Alkylation: Synthesis of Bio-based Symmetrical and Disymmetrical Ethers

For the first time, a reductive alkylation process in continuous flow has been elaborated for the conversion of bio-based alcohols and aldehydes into symmetrical and dissymmetrical high-value-added ethers for industrial companies. The developed method is an etherification associating liquid, solid and gas phases under green conditions (continuous flow, catalysis, bio-based starting materials).

Synthesis of ethers from esters via Fe-catalyzed hydrosilylation

Triiron dodecacarbonyl allows for the selective reduction of esters into the corresponding ethers. This protocol has a wide substrate scope. In addition, cholesteryl pelarogonate has been reduced under the reaction conditions with an excellent yield.

PROCESS FOR MAKING A COMPOSITION COMPRISING AT LEAST TWO DIFFERENT DIALKYL ETHERS

The present invention relates to a process for making a composition comprising at least two different ethers using ethanol, or a combination of ethanol and methanol, as a starting material.

Cu(OTf)2-catalyzed Et3SiH-reductive etherification of various carbonyl compounds with trimethylsilyl ethers

A triethylsilane-reductive etherification of the trimethylsilyl ethers with a variety of carbonyl compounds in good yields at room temperature employing 0.5 mol% Cu(OTf)2 as an extremely efficient catalyst is described here.

Zeolite-Promoted Benzylation of Alcohols

Zeolite-promoted benzylation of alcohols with benzyl chloride has been investigated.By use of a series of cation-exchanged zeolites, which have the same crystalline structure but different acid and base properties, it is confirmed that the cooperative function of acid sites and base sites of zeolite is required for the effective benzylation of alcohols, although both acid and base strengths are low.It is also found that alcohols show different reactivities in zeolite from those in solution depending on their molecular structures because the benzylation is promoted inside the narrow cavities of zeolite.