1708-23-2Relevant academic research and scientific papers
Metal-free coupling of saturated heterocyclic sulfonylhydrazones with boronic acids
Allwood, Daniel M.,Blakemore, David C.,Brown, Alan D.,Ley, Steven V.
, p. 328 - 338 (2014/01/17)
The coupling of aromatic moieties with saturated heterocyclic partners is currently an area of significant interest for the pharmaceutical industry. Herein, we present a procedure for the metal-free coupling of 4-, 5-, and 6-membered saturated heterocyclic p-methoxyphenyl (PMP) sulfonylhydrazones with aryl and heteroaromatic boronic acids. This procedure enables a simple, two-step synthesis of a range of functionalized sp2-sp3 linked bicyclic building blocks, including oxetanes, piperidines, and azetidines, from their parent ketones.
Synthesis of Several Isomeric Tetrathiafulvalene ?-Electron Donors with Peripheral Sulfur Atoms. A Study of Their Radical Cations
Rovira, Concepcio,Veciana, Jaume,Santalo, Nuria,Tarres, Judit,Cirujeda, Joan,et al.
, p. 3307 - 3313 (2007/10/02)
An efficient synthesis of one new (10) and three previously reported (9, 11, and 12) ?-electron donors, which have one sulfur atom in each of the outer five-membered rings attached to the TTF system, is presented.The radical cations derived from 9-11 have
