170952-87-1Relevant articles and documents
ADAMANTYL-CONTAINING THIOESTERS I. SYNTHESIS AND CHEMICAL TRANSFORMATIONS OF O-METHYL ADAMANTANE-1-CARBOTHIOATE
Klimko, Yu. E.,Isaev, S. D.,Yurchenko, A. G.
, p. 1776 - 1783 (2007/10/03)
O-Methyl adamantane-1-carbothioate was obtained for the first time by the reaction of methyl adamantane-1-carboxylate with phosphorus pentasulfide in dimethoxyethane or dioxane.Its reactions with hydroxylamine and O-methylhydroxylamine led to the preferential formation of 1-adamantyl cyanide and 1-adamantyl isothiocyanate respectively.The products from the reaction of the thioester with piperidine were the O-ester and piperidinium salt of adamantane-2-carbothioic O-acid, the formation of which was accompanied by N-alkylation of the amine.The reaction of the thioester and diazomethane gave adamantyl-containing thiadiazoles and thiadiazolines.