171089-39-7Relevant academic research and scientific papers
Photodecompostion of the Oligogermanes nBu3GeGePh2GenBu3 and nBu3GeGePh3: Identification of the Photoproducts by Spectroscopic and Spectrometric Methods
Komanduri, Sangeetha P.,Schrick, Aaron C.,Feasley, Christa L.,Dufresne, Craig P.,Weinert, Charles S.
, p. 3196 - 3203 (2016/07/14)
The oligogermane nBu3GeGePh2GenBu3was photolyzed using UV-C light in the presence of acetic acid as a trapping agent and the photoproducts were identified using1H NMR spectroscopy, gas chromatography/electron-impact mass spectrometry, and high resolution accurate mass mass spectrometry. The products identified were the germanes nBu3GeH, nBu3GeOAc, and Ph2Ge(H)OAc (OAc = C2H3O2) and the digermane nBu6Ge2. This indicates that both germanium–germanium single bonds are cleaved homolytically upon irradiation to generate two nBu3Ge·radicals and the germylene Ph2Ge:. The digermane nBu3GeGePh3was also photolyzed under identical conditions, and in this case the photoproducts were identified as nBu3GeH, nBu3GeOAc, Ph3GeH, Ph3GeOAc and the digermanes nBu6Ge2and Ph6Ge2.
The First Application of Samarium(II) Diiodide for the Formation of Group 14 Element Catenates: Synthesis of Tri- or Poly-germanes and Polystannanes
Yokoyama, Yasuo,Hayakawa, Masamichi,Azemi, Takushi,Mochida, Kunio
, p. 2275 - 2276 (2007/10/02)
Some Group 14 element catenates such as tri- or poly-germanes and polystannanes are synthesized by use of the one-electron reducing agent SmI2.
