1711-40-6Relevant academic research and scientific papers
One-pot epoxidation of alkenes using aerobic photoperoxidation of toluenes
Taguchi, Miyabi,Nagasawa, Yoshitomo,Yamaguchi, Eiji,Tada, Norihiro,Miura, Tsuyoshi,Itoh, Akichika
supporting information, p. 230 - 232 (2015/12/31)
We developed an aerobic photooxidative synthesis of peroxybenzoic acids from toluenes using anthraquinone-2-carboxylic acid (AQN-2-CO2H) as a photocatalyst. We also found a one-pot epoxidation reaction of alkenes using 4-tert-butylperoxybenzoic acid produced in situ by aerobic photooxidative synthesis.
Facile aerobic photooxidation of methyl group in the aromatic nucleus in the presence of an organocatalyst under VIS irradiation
Tada, Norihiro,Hattori, Kasumi,Nobuta, Tomoya,Miura, Tsuyoshi,Itoh, Akichika
supporting information; experimental part, p. 1669 - 1671 (2011/08/10)
We report a useful method for a facile synthesis of carboxylic acids from methyl aromatics by aerobic photooxidation using VIS irradiation and easily handled 2-chloroanthraquinone as organic catalysts under mild conditions such as an air atmosphere and ambient pressure and temperature. This is a more environmentally benign oxidation than previous methods, which require drastic reaction conditions.
