17120-54-6

Basic information

• Product Name: Benzyl 2-O,3-O-dibenzyl-β-D-galactopyranosiduronic acid
• Synonyms: Benzyl 2-O,3-O-dibenzyl-β-D-galactopyranosiduronic acid
• CAS NO: 17120-54-6
• Molecular Formula: C₂₇H₂₈O₇
• Molecular Weight: 464.50702
• Mol File: 17120-54-6.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzyl 2-O,3-O-dibenzyl-β-D-galactopyranosiduronic acid(CAS DataBase Reference)
• NIST Chemistry Reference: Benzyl 2-O,3-O-dibenzyl-β-D-galactopyranosiduronic acid(17120-54-6)
• EPA Substance Registry System: Benzyl 2-O,3-O-dibenzyl-β-D-galactopyranosiduronic acid(17120-54-6)

Safety Data

• Hazardous Substances Data: 17120-54-6(Hazardous Substances Data)

Upstream product

• 74801-06-2 benzyl 2,3-di-O-benzyl-4,6-ol-β-D-galactopyranoside 

Downstream Products

• 225640-49-3 methyl (benzyl 2,3,4-tri-O-benzyl-α-D-galactopyranosyluronate)-(1->4)-(benzyl 2,3-di-O-benzyl-β-D-galactopyranosid)uronate 
• 187031-86-3 benzyl (methyl 2,3,4-tri-O-benzyl-α-D-galactopyranosyluronate)-(1->4)-(benzyl 2,3-di-O-benzyl-β-D-galactopyranosid)uronate 
• 187031-74-9 benzyl (benzyl 2,3-di-O-benzyl-β-D-galactopyranosid)uronate 
• 17120-56-8 methyl (benzyl 2,3-di-O-benzyl-β-D-galactopyranosid)uronate 

Relevant articles and documents

Synthesis of the two monomethyl esters of the disaccharide 4-O-α-D-galacturonosyl-D-galacturonic acid and of precursors for the preparation of higher oligomers methyl uronated in definite sequences

Methyl (α-D-galactopyranosyluronic acid)-(1→4)-D-galactopyranuronate and methyl α-D-galactopyranosyluronate-(1→4)-D-galactopyranuronic acid have been synthesized by coupling methyl (benzyl 2,3-di-O-benzyl-β-D-galactopyranosid)uronate (3) or benzyl (benzyl 2,3-di-O-benzyl-β-D-galactopyranosid)uronate (4) with benzyl (phenyl 2,3,4-tri-O-benzyl-1-thio-β-D-galactopyranosid)uronate and methyl (phenyl 2,3,4-tri-O-benzyl-1-thio-β-D-galactopyranosid)uronate, respectively, using N-iodosuccinimide and trifluoromethanesulphonic acid as promoters, followed by removal of the benzyl groups. The 4'-OH unprotected dimers benzyl (methyl 2,3-di-O-benzyl-α-D-galactopyranosyluronate)-(1→4)-(benzyl 2,3-di-O-benzyl-β-D-galactopyranosid)uronate and methyl (benzyl 2,3-di-O-benzyl-α-D-galactopyranosyluronate)-(1→4)-(benzyl 2,3-di-O-benzyl-β-D-galactopyranosid)uronate were prepared from methyl (phenyl 2,3-di-O-benzyl-1-thio-4-O-trimethylsilyl-β-D-galactopyranosid)uronate and benzyl (phenyl 2,3-di-O-benzyl-1-thio-4-O-trimethylsilyl-β-D-galactopyranosid)uronate and acceptors 4 or 3, respectively. These compounds have been designed to serve as precursors for the preparation of higher-membered d-galacturonic acid oligomers methyl esterified in definite positions. Copyright (C) 1998 Elsevier Science Ltd.