17136-91-3Relevant academic research and scientific papers
I--catalyzed reaction of 5-methoxyoxazoles with organic iodides - An efficient synthesis of azalactones
Lu, Lianghua,Lu, Ping,Shengming, Ma
, p. 676 - 680 (2007/10/03)
An I--catalyzed methoxy carbon-oxygen bond cleavage in 5-methoxyoxazoles leading to the synthesis of azalactones, precursors of quaternary amino acids, has been developed. A series of 4-substituted azalactones were obtained through the variatio
Kinetic resolution displaying zeroth order dependence on substrate consumption: Copper-catalyzed asymmetric alcoholysis of azlactones
Tokunaga, Makoto,Kiyosu, Junya,Obora, Yasushi,Tsuji, Yasushi
, p. 4481 - 4486 (2007/10/03)
Kinetic resolution of 4-alkyl-2-aryl-5-oxo-4,5-dihydrooxazole-4-carboxylic acid esters (azlactones 1) were achieved by copper-DTBM-SEGPHOS catalyzed alcoholysis reaction with good selectivity (12 examples). Variation of ee of unreacted substrates 1 and pr
