171360-62-6

Basic information

• Product Name: 2-acetylamino-1-methoxycarbonyl-2-thioxoethylidenotriphenylphosphorane
• Synonyms: 2-acetylamino-1-methoxycarbonyl-2-thioxoethylidenotriphenylphosphorane
• CAS NO: 171360-62-6
• Molecular Weight: 435.483
• Mol File: 171360-62-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-acetylamino-1-methoxycarbonyl-2-thioxoethylidenotriphenylphosphorane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-acetylamino-1-methoxycarbonyl-2-thioxoethylidenotriphenylphosphorane(171360-62-6)
• EPA Substance Registry System: 2-acetylamino-1-methoxycarbonyl-2-thioxoethylidenotriphenylphosphorane(171360-62-6)

Safety Data

• Hazardous Substances Data: 171360-62-6(Hazardous Substances Data)

Upstream product

• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 
• 13250-46-9 acetyl isothiocyanate 

Downstream Products

• 171360-72-8 methoxycarbonyl(4-phenylthiazole-2-yl)-methylenetriphenylphosphorane 
• 171360-64-8 (methoxycarbonyl)thiocarbamoylmethylenotriphenylphosphorane 

Relevant articles and documents

Heterocyclizations with C-thiocarbamoyl-substituted derivatives of phosphonium ylides

We found an easy method for conducting the Ph3P=C(X)H -> -> Ph3P=C(X)C(S)NH2 transformation that is based on treating accessible phosphonium ylides first with acetyl isothiocyanate and then with sodium hydroxide.New thiocarbamoyl-containing reagents readily enter into cyclocondensation with α-halocarbonyl compounds and chloroacetonitrile; this property was used for synthesizing a number of stabilized ylides of the general formula Ph3P=C(X)Ht.