17147-67-0Relevant academic research and scientific papers
Substituted 5-dinitromethyl-3-phenyl-1,2,4-oxadiazoles in reactions with arylethenes
Tyrkov
, p. 890 - 892 (2007/10/03)
Reactions of substituted 5-dinitromethyl-3-phenyl-1,2,4-oxadiazoles with arylethenes of various nucleophilicity, number and position of substituents attached to the double bond give rise to nitroalkenes and secondary products resulting from α-nitroketones or nitroalcohols O-alkylation. The direction of transformations in the arising ion pair is governed predominantly by steric effects.
A novel one pot synthesis of α-nitroketones from olefins using trimethylsilylnitrate-chromium trioxide reagent system
Reddy, M. Venkat Ram,Kumareswaran,Vankar, Yashwant D.
, p. 7149 - 7152 (2007/10/02)
A variety of α-nitroketones have been obtained from the corresponding olefins in good yields upon reaction with trimethylsilylnitrate-chromium trioxide reagent system.
Kinetics of reactions of hydroxide ion and water with β-X-substituted α-nitrostilbenes (X = Cl, I, SEt, OMe, SCH2CH2OH) in 50% Me2SO-50% water. Search for the intermediate in nucleophilic vinylic substitution
Bernasconi, Claude F.,Fassberg, Julianne,Killion Jr., Robert B.,Schuck, David F.,Rappoport, Zvi
, p. 4937 - 4946 (2007/10/02)
The hydrolysis of Ph(LG)C=Cph(NO2) (4-LG, Lg = Cl, I, Set, Ome) in basic solution yields the anion of 1,2-diphenyl-2-nitroethanone, PhC(=O)C(=NO2-)Ph (8-), by the addition-elimanation mechanism of nucleophilic v
