17159-99-8Relevant academic research and scientific papers
Mechanistic insights into palladium leaching in novel Pd/C-catalyzed boron-heck reaction of arylboronic acid
Dighe, Mahesh G.,Lonkar, Sachin L.,Degani, Mariam S.
, p. 347 - 350 (2013)
For the first time, Pd/C has been used for the Boron-Heck reaction, and the detailed mechanistic aspects of the reaction have been proven experimentally by a leaching test as well as by cyclic voltammetry studies. The results indicate that palladium leaching as a Pd(II) species, by oxidative addition of the arylboronic acid, is responsible for the reaction. Georg Thieme Verlag Stuttgart - New York.
Pd-diimine: A highly selective catalyst system for the base-free oxidative heck reaction
Gottumukkala, Aditya L.,Teichert, Johannes F.,Heijnen, Dorus,Eisink, Niek,Van Dijk, Simon,Ferrer, Catalina,Van Den Hoogenband, Adri,Minnaard, Adriaan J.
supporting information; experimental part, p. 3498 - 3501 (2011/06/22)
Pd(OAc)2/3 is an efficient catalyst system for the base-free oxidative Heck reaction that outperforms the currently available catalysts for the more challenging substrates studied. The catalyst system is highly selective, and works at room temperature with dioxygen as the oxidant.
