17162-84-4

Upstream product

• 17162-83-3 N-(diphenylphosphinothioyl)-P,P-diphenylphosphinic amide 
• 7648-76-2 (diphenylphosphinoamino)diphenylphosphine oxide 

Downstream Products

• 220171-69-7 Pd((CH₃)2NC₁₀H₆)(N(P(O)(C₆H₅)2)P(S)(C₆H₅)2) 
• 220171-67-5 Pd((CH₃)2NCH₂C₆H₄)(N(P(O)(C₆H₅)2)P(S)(C₆H₅)2) 
• 220171-71-1 PdCl(P(CH₃)2C₆H₅)(N(P(O)(C₆H₅)2)P(S)(C₆H₅)2) 
• 220171-92-6 Pd(((C₆H₅)2PCH)2)(N(P(O)(C₆H₅)2)P(S)(C₆H₅)2)⁽¹⁺⁾*PF₆^(1-)=[Pd(((C₆H₅)2PCH)2)(N(P(O)(C₆H₅)2)P(S)(C₆H₅)2)]PF₆ 
• 242795-48-8 Pt(P(C₆H₅)3)2((C₆H₅)2P(O)NP(S)(C₆H₅)2)⁽¹⁺⁾*PF₆^(1-) = [Pt(P(C₆H₅)3)2((C₆H₅)2P(O)NP(S)(C₆H₅)2)][PF₆] 
• 280124-37-0 Pd[Ph₂P(O)NP(S)Ph₂-S]2(1,2-diaminocyclohexane) 
• 371777-86-5 (C₆H₅)3Pb[(OP(C₆H₅)2)(SP(C₆H₅)2)N] 
• 269058-79-9 [Pd(C₉H₁₅O)((C₆H₅)2PSNPO(C₆H₅)2)] 
• 280124-46-1 Pd[Ph₂P(O)NP(S)Ph₂-O,S](N,N,N',N'-tetramethylethylenediamine) 
• 220171-71-1 N(P(C₆H₅)2)2(O)(S)PdClP(CH₃)2(C₆H₅) 
• 220171-63-1 Pd((C₅H₄N)2)(N(P(O)(C₆H₅)2)P(S)(C₆H₅)2)⁽¹⁺⁾*PF₆^(1-)=[Pd((C₅H₄N)2)(N(P(O)(C₆H₅)2)P(S)(C₆H₅)2)]PF₆ 
• 207741-98-8 [Pd(H₂NCH₂CH₂NH₂)((C₆H₅)2P(O)NP(S)(C₆H₅)2)2] 

Relevant academic research and scientific papers

The first crystal structures of mixed chalcogen derivatives SnR22 (R = Me or Ph)

The compounds SnR22 (R = Me, n-Bu, CH2Ph or Ph) were prepared by metathesis reactions between SnR2Cl2 and K in toluene.Reactions between SnR3Cl (R = Me or Ph) and K (1:1 molar ratio) in boiling toluene also produced the dimethyl- and diphenyl-tin(IV) derivatives as redistribution products.The same reactions in chloroform at room temperature afford the corresponding triorganotin(IV) compounds.The compounds were characterized by means of IR and multinuclear NMR spectroscopy.The crystal and molecular structures of SnR22 (R = Me 1 or Ph 2) derivatives were determined by X-ray diffractometry.Both compounds exhibit very similar spiro-bicyclic structures, with the tin atom as spiro atom.The ligand moieties are monometallic biconnective (bidentate) through both oxygen and sulfur atoms .The co-ordination geometry around the central metal atom is octahedral, with C-Sn-C, O-Sn-O (trans) and S-Sn-S (trans) angles of 180 deg.The conformation of the six-membered SnOSP2N inorganic rings is twisted boat.

Complexes of - (E = S or Se): Disparate Ring Conformations within a New Palladacycle

A new mixed oxygen-selenium ligand Ph2P(O)NHP(Se)Ph2, its potassium salt K and the bis(chelate) palladium(II) complex cis-2> have been prepared.In cis-2> the two cis six-membered Pd-O-P-N-P-Se rings adopt different conformations; one is a pseudo-boat whilst the other is chair-like (X-ray evidence).Reaction of 2 equivalents of K with (cod = cycloocta-1,5-diene) in MeOH, or more conveniently using the methoxo-bridged platinum(II) dimer 2> (C8H12OMe = 8-methoxycyclooct-4-en-1-yl), afforded > as one isomer only.The mixed oxygen-sulfur salt K was used to prepare similar compounds, all of which have been characterised by a combination of multinuclear NMR ((31)P-, (195)Pt- and (1)H), IR spectroscopy and microanalysis.The molecular structures of Ph2P(O)NHP(S)Ph2, cis-2> and > have been determined by single-crystal X-ray diffraction.