17181-80-5Relevant academic research and scientific papers
[1,2]-Wittig rearrangement of a lithioalkyl benzyl ether with inversion of configuration at the carbanion C atom. Diastereoselective reductions of cyclohexyl radicals with LI+ arene-
Hoffmann, Rolf,Rueckert, Tanja,Brueckner, Reinhard
, p. 297 - 300 (1993)
Treatment of the diastereomeric O, Se-ketals cis- or trans-4 with lithium naphthalenide provided, through stereoselective reduction of the radical intermediate 5, the axially lithiated cyclohexyl ether trans-6. trans-6 gave the equatorially benzylated cyc
