171863-69-7Relevant academic research and scientific papers
Highly stereocontrolled total synthesis of (+)-bengamide E
Mukai, Chisato,Moharram, Sameh M.,Kataoka, Osamu,Hanaoka, Miyoji
, p. 2849 - 2854 (2007/10/02)
Diisopropyl D-tartrate 7 was efficiently transformed into the hexacarbonyl dicobalt complexed aldehyde 23.A highly stereocontrolled aldol reaction of 23 with the O,S-acetal 20 in the presence of tin(IV) chloride provided, after decomplexation, the aldol adduct 21 as the sole product, which was subsequently converted into (+)-bengamide E 5.
