171868-16-9Relevant academic research and scientific papers
Asymmetric addition of diethylzinc to ketones promoted by tartaric acid derivatives
Hui, Ailing,Zhang, Jintang,Wang, Zhiyong
, p. 2374 - 2384 (2008/09/21)
The preparation of new sulfonamide ligands derived from L-tartaric acid and camphor sulfonyl chloride are described. The employment in the titanium tetraisopropoxide-promoted enantioselective addition of diethylzinc to ketones has been studied. The best enantiomeric excess is up to 99% with 7 mol% catalyst loading at room temperature. Copyright Taylor & Francis Group, LLC.
