17190-15-7Relevant academic research and scientific papers
Rearrangement of acyloxyoxiranes: A revised structure for the oxidation product of 5α-androst-16-ene-3α,17-diol 3-benzoate 17-acetate
Subbaraju,Urbanczyk-Lipkowska,Newaz,Manhas,Bose
, p. 10087 - 10092 (2007/10/02)
During the oxidation of conjugated enones to α-acyloxyoxiranes by m-chloroperbenzoic acid, the preferred sequence is epoxidation followed by Baeyer-Villiger oxidation. Rearrangement of acyloxyoxiranes to α-acyloxyketones, in situ, was observed. The α-keto
