171975-59-0Relevant articles and documents
Pentafluorophenylplatinum Complexes containing η1- or η2-Aryl-Pt Interactions. Crystal Structure of cis-2-Ph)Ph>-2>-κN)>*0.5C6H5Me
Casas, Jose M.,Fornies, Juan,Martin, Antonio,Menjon, Babil,Tomas, Milagros
, p. 2949 - 2954 (2007/10/03)
The reaction of cis-> 2 and cis-> 3 respectively.The solid-state structure of 2 has been established by X-ray diffraction methods and reveals the existence of a η2-phenyl-Pt interaction which is maintained in solution (NMR).Crystal data for 2*0.5C6H5Me: C33.5H19F10NPt, triclinic, space group P, a = 11.653(4), b = 12.345(3), c = 12.499(4) Angstroem, α = 116.91(2), β = 104.33(2), γ = 103.41(2) deg, Z = 2, R =0.038 for 2791 unique 'observed' absorption-corrected reflections collected at 233 K.Complexes 2 and 3 reacted with CO yielding cis-(CO)> and cis-(CO)> respectively.